Search results for "Lead–acid battery"
showing 9 items of 9 documents
Template electrodeposition and characterization of nanostructured Pb as a negative electrode for lead-acid battery
2019
Abstract Despite Lead Acid Battery (LAB) is the oldest electrochemical energy storage system, diffusion in the emerging sectors of technological interest is inhibited by its drawbacks. The principal ones are low energy density and negative plate sulphating on high rate discharging. In this work, it is shown the possibility of overcoming such drawbacks by using nanostructured lead as a negative electrode. Lead nanowires (NWs) were fabricated by electrochemical deposition in template, which is an easy, cheap, and easily scalable process. Their morphology and crystal structure have been characterized by electron microscopy and X-ray diffraction, respectively. An electrochemical cell simulating…
Processes during preparation of lead/acid battery positive plates from tetrabasic lead sulfate (4BS) pastes
1993
Abstract Tthe processes studied during this investigation were paste mixing and curing. Tetrabasic lead sulfate 4BS pastes were prepared by solution and paste methods both from α-PbO and mill oxides, and the development of 4BS was carried out already during the paste mixing stage. the 4BS pastes were characterized by SEM, TEM, XRD and wet-chemical methods, and the results were compared with those obtained from the characterization of corresponding tribasic lead sulfate (3BS) pastes. The preparation method was found to be one dominating factor affecting both the morphology and structure of 4BS active masses. The selection of raw material gave an additional effect on the morphology. Additiona…
Metallic lead recovery from lead-acid battery paste by urea acetate dissolution and cementation on iron
2009
Abstract A suitable hydrometallurgical and environmentally friendly process was studied to replace the currently used practices for recycling lead-acid batteries via smelting. Metallic lead was recovered by cementation from industrial lead sludge solutions of urea acetate (200 to 500 g/L) using different types of metallic iron substrates (nails, shaving or powder) as reducing agents. Under specific operating conditions, up to 99.7% of lead acid battery paste, mainly composed of PbSO4, PbO2 and PbO·PbSO4 species, was converted to metallic lead.. The conversion of the metallic lead and rate of the cementation reaction were strictly dependent on the type of iron substrate used as the reductant…
Behavior Modification of Nanostructured PbO2 Electrodes in Lead Acid Batteries Changing Electrolyte Concentration and Separator
2019
Currently, lead acid battery is extensively investigated owing to its prevalent use as a startinglighting and ignition device. An essential role for electrochemical reactions is played by the surface area available for conversion reactions and a possible approach is the use of nanostructured electrodes. In this work, lead dioxide nanostructured electrodes were tested in order to investigate the dependence of the charge and discharge behaviour on some parameters such as electrolyte concentration, and a new type of thin separator. In this last case, it is possible to reduce the size of the cell by using a very thin separator comparable to the nanostructured electrode thickness. Besides, a low…
High-performance of PbO2 nanowire electrodes for lead-acid battery
2014
Abstract PbO2 nanowires were obtained by template electrodeposition in polycarbonate membranes and tested as positive electrode for lead-acid battery. Nanowires were grown on the same material acting as current collector that was electrodeposited too. The nanostructured electrodes were assembled in a zero-gap configuration using commercial negative plate and separator. Cell performance was tested by galvanostatic charge/discharge cycles in a 5 M H2SO4 aqueous electrolyte. PbO2 nanostructured electrodes were able to deliver at 1C rate an almost constant capacity of about 190 mAh g−1 (85% of active material utilization), close to the theoretical value (224 mAh g−1). The nanowire array provide…
Recent improvements in PbO2 nanowire electrodes for lead-acid battery
2015
Abstract Lead oxide nanowires are an attractive alternative to conventional pasted electrodes, owing to their high surface area leading to high specific energy batteries. Here, we report the performance of template electrodeposited PbO 2 nanowires used as positive electrodes. Nanostructured electrodes were tested at constant charge/discharge rate from 2 C to 10 C, with a cut-off potential of 1.2 V and discharge depth up to 90% of the gravimetric charge. These new type of electrodes are able to work at very high C-rate without fading, reaching an efficiency of about 90% with a very good cycling stability. In particular, after an initial stabilization, a specific capacity of about 200 mAh g −…
Nanostructured lead acid battery for electric vehicles applications
2017
This paper presents an innovative lead acid battery, based on nanostructured active materials. Both charging time and specific energy are greatly enhanced in comparison with commercial lead acid battery. Starting from the extremely valuable performances of the nanostructured battery, also a circuital model, for application in electric vehicle traction, has been specifically developed. The circuital model has demonstrated that an enhanced nanostructured battery allows an increase of traveled distance by electric vehicles.
Performance of Lead-Acid Batteries with Nanostructured Electrodes at Different Temperature
2018
In this work we present innovative lead-acid batteries with nanostructured electrodes, which are cycled in a wide range of temperatures typically of lead-acid commercial batteries (EN 61427-1: 2013). In comparison to parameters usually used to commercial batteries, much more stressful conditions in terms of cut-off, charge/discharge rate and discharge were imposed.
High-Performance Lead-Acid Batteries Enabled by Pb and PbO2 Nanostructured Electrodes: Effect of Operating Temperature
2021
Lead-acid batteries are now widely used for energy storage, as result of an established and reliable technology. In the last decade, several studies have been carried out to improve the performance of this type of batteries, with the main objective to replace the conventional plates with innovative electrodes with improved stability, increased capacity and a larger active surface. Such studies ultimately aim to improve the kinetics of electrochemical conversion reactions at the electrode-solution interface and to guarantee a good electrical continuity during the repeated charge/discharge cycles. To achieve these objectives, our contribution focuses on the employment of nanostructured electr…